The blistering damage tends to form parallel to the surface and to the direction of hoop stress. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Wet hydrogen sulfide cracking is a term used for a variety of stress corrosion cracking scc failure modes of carbon steel exposed to aqueous sour refinery environments.
Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide and sulfur compounds. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials when the environment contains wet h 2 s. Environmental cracking is a broad term that includes corrosion fatigue, hightemperature hydrogen attack, hydrogen blistering, hydrogen embrittlement, liquid metal embrittlement, season cracking, caustic embrittlement, stress corrosion cracking, stepwise cracking, sulfide corrosion cracking and sulfide stress cracking. Materials and corrosion trends in offshore and subsea oil and. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Sulfide stress cracking ssc also known as sour gas cracking sour gas. Also, atomic hydrogen dissolved in the steel lattice may embrittle areas of hard microstructures in carbon steel base metal or weldments. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking. It is a dangerous type of corrosion which produces some of the toughest technical.
Sulfide stress cracking ssc can occur when h2s is present in the reservoir and is in contact with highstrength steel commonly used in drilling, completing and production wells 1. Most of the attributions of the role of hydrogen in ssc are based on similar cracking. Absorbed hydrogen atoms could easily provoke different types of hydrogen damage followed by environmentallyassisted cracking, apart from hic, including also sulfide stress cracking ssc and. Mechanisms that have been proposed to explain embrittlement include the formation. Sulfide stress cracking an overview sciencedirect topics. Feb 10, 2014 environmental degradation of materials by dr. Factors affecting the sulfide stress cracking performance. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The authors conducted extensive analyses to explore the effects of metallurgical factors on the resistance of line pipe steels to hydrogen induced cracking hic and sulfide stress cracking ssc. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Kallol mondal,department of metallurgy and material science,iit kanpur. Jul 25, 2017 it is now well known that ssc is a particular form of hydrogen stress cracking hsc in the presence of water and h 2 s.
One of the types of material damage that can occur as a result of hydrogen charging is sulfide stress cracking ssc of hard weldments and microstructures, which is. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide. Standard material requirements materials resistant to sulfide. Sulfide stress cracking, stress corrosion cracking, and other mechanisms of cracking caused by h2s. The variation of the name is due to the lack of agreement in the mechanism of failure. Mechanisms of alternating current induced corrosion of carbon steel publication. Sulfide stress cracking wikipedia republished wiki 2. As seen in figure 1, cracking was observed only on the tension side of ubend samples. Atomic hydrogen either combines to form h2 at the metal surface or diffuses into. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. The influence of chemical composition and microstructure of api linepipe steels on hydrogen induced cracking and sulfide stress corrosion cracking.
Standard material requirements materials resistant to. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Iron is oxidized to the ferrous form at the anode and hydrogen sulfide undergoes a two step dissociation at the cathode as shown below. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. Computer software ace apps for corrosion engineers has a module to determine when pwht or preheating is required. The mechanism of sulfide stress cracking involves a combination of stress corrosion cracking and hydrogen embrittlement. Abstract sulfide stress corrosion cracking ssc behavior of line pipe steel was investigated using the ssc test method in nace standard tm017777, testing of metals for resistance to sulfide. Sulfide stress cracking mostly occurs in very highly acidic environments. Sulfide stress cracking nace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. Hydrogen embrittlement also known as hydrogen assisted cracking and hydrogeninduced cracking, describes the embrittling of metal after being exposed to hydrogen. Hydrogen sulfide hsub 2s has long been associated with the cause of corrosion damage and sulfide stress cracking ssc in high strength steels and high hardness weldments used in oil and gas production, petroleum refining, and petrochemicalchemical processing. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require.
Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Sulfide stress cracking nace mr01752002, mr0175iso. Modeling and experimental insights of sulfide stress cracking. Sulfide stress cracking of nickelcontaining lowalloy. Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour. High atomic hydrogen concentrations in carbon steel can lead to sulfide stress cracking ssc of these hard areas. Sulfide stress cracking, modeling mechanism, octg martensitic pipes, kinetic of crack propagation, trapped and diffusible hydrogen overview quenched and tempered martensitic steels for oil country tubular goods can be subject to sulfide stress cracking when exposed to a sour environment. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism.
The low alloy steels of steam turbine rotors are susceptible to scc in the presence of hydroxides such as naoh. Hydrogen sulfide is a corrosive compound that can lead to sulfide stress cracking and promote hydrogen embrittlement. Hydrogen embrittlement is a function of the hydrogen absorption characteristics of the metal in the aggressive environment, which is the formation of molecular hydrogen from atomic hydrogen within the metal structure 160. One of these chemical reactions involves hydrogen sulfide in sulfide stress cracking ssc, a significant problem for the oil and gas industries.
Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Wet hydrogen sulfide h2s cracking inspectioneering. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. Rosen 15 types of pipeline cracks inspection solutions. The scope of the journal includes the latest developments in areas of corrosion metallurgy, mechanisms, predictors, cracking sulfide stress, stress corrosion, hydrogeninduced, passivation, and co 2 corrosion. Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches. Polythionic acid stress corrosion cracking deterioration. The responsibility for safe application of alloys is defined as follows. This is because insp 3 is linked to amine cracking ascc, which belongs to a related dme i. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The h2s causes the hydrogen to enter the metal structure rather than bubble off from the surface. This is because insp 2 is linked to 581 sulfide stress cracking, which belongs to the same dme as 581amine cracking i. Explains caustic embrittlement, season cracking, hydrogen embrittlement. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low.
Nov 11, 2018 this explains the stress corrosion and the conditions. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. For ssc to occur, a metal must be exposed to hydrogen sulfide and under operating conditions conducive to ssc. More extensive use of the wet fluorescent magnetic particle technique in recent years as a refinery equipment inspection tool has highlighted the extent and magnitude of the.
Sulfide stress corrosion cracking, also known as sulfide stress cracking ssc, is a stress corrosion cracking phenomena that occurs in the presence of hydrogen sulfide. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. There is a general agreement that plastic strain affects the resistance to sulphide stress cracking, even possibly for low amounts of strain and without significant changes in hardness. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen sulfide at low ph. Scc is most commonly seen on steam turbine disk blade root attachments. Some researchers consider sulfidestress cracking a type of stresscorrosion cracking, while others consider it a type of hydrogen embrittlement. This standard presents metallic material requirements to provide resistance to sulfide stress cracking ssc andor stress corrosion cracking scc for petroleum production, drilling, gathering and flow line equipment, and field processing facilities to be used in hydrogen sulfide h2sbearing hydrocarbon service.
A method for field evaluation of heat treatment to identify. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Segregation induced cracking occurs when low melting point constituents such as phosphorous, zinc, copper and sulfur compounds in the admixture separate during the weld solidification process. These three cracking mechanisms are known as sulfide stress cracking ssc, hydrogeninduced cracking hic, and stress oriented hydrogen induced cracking sohic. One of the more common problems is ssc, sulfide stress cracking. Ssc is a form of spontaneous brittle breakdown in occurring in highstrength. There is a wide range of damage mechanisms that can occur due to the effect of hydrogen charging in wet h2s environments. This type of cracking is referred to as stress oriented hydrogen induced cracking sohic. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. This mechanism is referred as sulfide stress corrosion cracking sscc. Highstrength steels with improved sulfide stress cracking resistance.
Sulfide stress cracking nace mr01752002, mr0175iso 15156. These high strength steels may break due to sulfide stress cracking ssc if subjected to mechanical stress and an aggressive environment which depends on the h2s partial pressure and solution ph. Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour service environments. Clscc chloride stress corrosion cracking mechanism china. Is sulfide stress cracking an anodic or a cathodic process. The first three cracking mechanisms are associated with the entry of atomic hydrogen into the carbon steel lattice. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. Sulfide stress cracking resistance of 95 and 110 ksi octg sour service grades under high partial pressure of h 2 s a contribution to corrosion mechanism understanding. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen.
Sulfide stress cracking ssc is just one of several forms of hydrogen. Sulfide stress cracking resistance of 95 and 110 ksi octg. Sulfide stress cracking oil and gas pipelines wiley. This phenomenon is a form of hydrogen embrittlement he that includes a crack initiation followed by a propagation step leading to failure.
Manufacturers and suppliers provide materials that meet. Ansinace mr0175hd2003sg metals for sulfide stress cracking. Sulfide stress corrosion cracking of line pipe corrosion. Mechanisms of sulfide stress cracking from the above discussion, it would appear fortuitous that hydrogen is intimately connected with ssc failure. It should not be confused with the term stress corrosion cracking which is an anodic. Sulfide stress cracking, amine cracking, polythionic acid, carbonate cracking, wet h2s cracking. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible.
Sulfide stress cracking of highstrength steels in laboratory. Abstract sulfide stress corrosion cracking ssc behavior of line pipe steel was investigated using the ssc test method in nace standard tm017777, testing of metals for resistance to sulfide stre. Pdf sulfide stress corrosion cracking and hydrogen. Effect of coldwork on sulphide stress cracking resistance. Three different mechanisms involved in stress corrosion. Corrosionpedia what is sulfide stress cracking ssc. Other mechanisms of introduction of hydrogen into metal are galvanic corrosion, as well as chemical reactions with acids or other chemicals. Dunlop, thus, concluded that the eac mechanism was a form of scc, i. Dunlop named this type of eac sulfide corrosion stress cracking scsc, which is now an obsolete term. Sulfide stress cracking of nickelcontaining lowalloy steels. Sulfide stress cracking sulfide stress cracking ssc occurs only on high strength hardness steels. Under the assumption that these vessels were adequately heat treated, the vessels owners do not normally take into consideration the high residual stresses which create favorable conditions for sulfide stress cracking ssc and other stress corrosion cracking type damage mechanisms. Modeling and experimental insights of sulfide stress. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress.
Sscc is a specialized case of hydrogen cracking as it may be possible that sulfide stress corrosion cracking and hydrogen cracking proceed simultaneously. Control of stress level residual or load and hardness. In parallel events, once atomic hydrogen is absorbed within the microstructure, it can also diffuse into solid solution, leading to local crystal embrittlement and ultimately stress corrosion cracking in the presence of residual or applied tensile stresses. H 2 s can cause sulfide stress cracking of stainless steels. As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment that comes in contact with sour wet h2s service conditions.